The Open Colloid Science Journal

2010, 3 : 9-14
Published online 2010 April 20. DOI: 10.2174/1876530001003010009
Publisher ID: TOCOLLSJ-3-9

Microemulsions with Nonionic Surfactants and Mint Oil

Monzer Fanun
Colloids and Surfaces Research Laboratory, Faculty of Science and Technology, Al-Quds University, 51000 East Jerusalem, Palestine

ABSTRACT

A combination of electrical conductivity, dynamic viscosity, dynamic light scattering and small angle X-ray scattering methods was used to study the properties of the water + propylene glycol/mixed nonionic surfactants/ peppermint oil + ethanol U-type microemulsions which can be diluted with any amount of water. The surfactants were sucrose laurate and ethoxylated mono-di-glyceride. The mixing ratios (w/w) of the mixed surfactants and peppermint oil/ethanol equal unity and that of water/propylene glycol equals to two. The electrical conductivity and periodicity of the microemulsions increases with the aqueous phase content while the dynamic viscosity decreases. The variations in the values of the correlation length with the aqueous phase contents indicate the onset of structural transitions. Structural transitions from the water-in-oil to a bicontinuous phase then inversion to oil-in-water occurs in the system.

Keywords:

Phase behaviour, hydrodynamic radius, periodicity, correlation length, structural transitions.