The Open Chemical Physics Journal

2008, 1 : 23-28
Published online 2008 April 30. DOI: 10.2174/1874412500801010023
Publisher ID: TOCPJ-1-23

Optical Features of Substituted Phenyl End-Capped Oligothiophenes

E.V. Canesi , G. Dassa , C. Botta , A. Bianco , C. Bertarelli and G. Zerbi
Dipartimento di Chimica, Materiali e Ingegneria Chimica “G. Natta”, Piazza L. Da Vinci 32, 20133 Milano, Italy.

ABSTRACT

A series of phenyl end-capped oligothiophenes has been synthesized and a study of the absorption and emission properties has been carried out; the photoluminescence quantum yield has been measured both in solution and in solid state. The characterization, supported by DFT calculations, highlights a strong relationship between the optical features and the differences in the chemical structure. The results show that some molecules are of interest in the field of organic light emitting diodes (OLEDs).